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Research Article

ScienceAsia 22 (1996): 163-168 |doi: 10.2306/scienceasia1513-1874.1996.22.163

RATIO BETWEEN THE JUMP IN THE SPECIFIC HEAT AND THE THERMODYNAMIC CRITICAL FIELD FOR THE DOPED FULLERENE SUPERCONDUCTORS

I. M. TANG

ABSTRACT: The jump in the specific heat at T, and the critical fields of Type II superconductors are connected through a thermodynamic relation. The relationship leads to (C/Tc) = [dH2(Tc)/dT]2/822 where Hc2(T) is the upper critical field and is the ratio between the penetration depth and coherence length. Application of this equation to the critical field data for the doped fu/lerene superconductor K3C60 yields a value for C/Tc, of 380 mJ/mole/K2 which is far above the measured value of 68 13 mJ/mole/K2. We find that this discrepancy could be due to the electrons in the alkali doped fullerene superconductor being coupled to both a high intramolecular vibration mode and a low lying intermolecular vibration mode. The strong coupling Eliashberg formalism is used.

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Faculty of Science, Mahidol University, Rama VI Road, Bangkok 10400, Thailand and
Institute of Science and Technology for Research and Development, Mahidol University, Nakorn Pathom 73170, Thailand.

Received April 17, 1996